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DESS-MARTIN PERIODINANE |
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PRODUCT IDENTIFICATION |
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| CAS NO. | 87413-09-0 |
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| EINECS NO. | ||
| FORMULA | C13H13IO8 | |
| MOL WT. | 424.14 | |
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H.S. CODE |
2916.39.4500 | |
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TOXICITY |
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| SYNONYMS | (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one; | |
| Triacetoxyperiodinane; | ||
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SMILES |
O(C(C)=O)I1(OC(c2c1cccc2)=O)(OC(=O)C)OC(=O)C | |
CLASSIFICATION |
Hypervalent Iodine. | |
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EXTRA NOTES |
Oxidizing agent for primary and secondary alcohols to aldehydes and ketones. Used for the oxidation of hydroxychlorins to chlorin-alpha-diones and tetraones. |
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PHYSICAL AND CHEMICAL PROPERTIES |
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| PHYSICAL STATE | white to off-white crystalline powder | |
| MELTING POINT |
131 - 134 C |
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| BOILING POINT | ||
| SPECIFIC GRAVITY | 1.362 | |
| SOLUBILITY IN WATER | ||
| SOLUBILITY IN SOLVENT | Sparingly soluble in hexane, ether. Soluble in chloroform, methylene chloride, acetonitrile and acetone. | |
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AUTOIGNITION |
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NFPA RATINGS |
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REFRACTIVE INDEX |
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| FLASH POINT |
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| STABILITY |
Stable under ordinary conditions. |
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GENERAL DESCRIPTION AND EXTERNAL LINKS |
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Wikipedia Linking: http://en.wikipedia.org/wiki/Dess-Martin_periodinane Material Safety Data Sheet: http://www.chemcas.com Dess-Martin Oxidation: The Dess-Martin Periodinane (DMP), a hypervalent iodine compound, offers selective and very mild oxidation of alcohols to aldehydes or ketones. The oxidation is performed in dichloromethane or chloroform at room temperature, and is usually complete within 0.5 - 2 hours. Products are easily separated from the iodo-compound byproduct after basic work-up. http://www.organic-chemistry.org/ |
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| SALES SPECIFICATION | ||
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APPEARANCE |
white to off-white crystalline powder | |
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ASSAY |
97.0% min | |
| MELTING POINT | 131 - 134 C |
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| TRANSPORTATION | ||
| PACKING |
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| HAZARD CLASS | ||
| UN NO. | ||
| OTHER INFORMATION | ||
| Hazard Symbols: O, XN, Risk Phrases: 8-40, Safety Phrases: 17-23-24/25-36/37 | ||
